山西大学环境科学与工程研究中心

针对环境科学中一系列分析测试的关键科学问题，近年来开展了以功能纳米材料（如鈀纳材料，石墨烯及其量子点）为核心的电化学催化、化学与生物传感研究工作，主要围绕环境污染物（甲烷和抗生素）的实时监控、降解和前期预警等重要信息处理，重点从纳米电化学技术基础、传感信号放大机制、生物传感界面构建以及传感检测技术等方面入手，在污染物分析、纳米信号放大、生物分子的设计与界面组装和功能器件的构建等领域取得重要成果，实现了环境污染物和生物标志物的高灵敏、廉价、快速和实时检测。

在相关领域期刊发表论文30余篇（其中SCI检索23篇），申请中国专利13项（已授权6项）。同时在应用技术合作研发方面具有一定的实际应用和产业化经验。

论文：

[1]Wenwen Yi, Chunxiao Han, Zhongping Li, * Yujing Guo,* Meng Liu and Chuan Dong, A strategy of electrochemical simultaneous detection of acetaminophen and levofloxacin in water based on g-C3N4nanosheet-doped graphene oxide, Environmental Science Nano, 2021, 8, 258-268. DOI: 10.1039/d0en00858c (Impact factor: 7.683 1区Top)

[2]Liying Wang, Kaiyun Song, Yuanyuan Qu, Yangyang Chang, Zhongping Li, Chuan Dong, Meng Liu,* John D. Brennan, and Yingfu Li*, Engineering Micrometer-Sized DNA Tracks for High-Speed DNA Synthesis and Biosensing, Angew. Chem. Int. Ed. 2020, 59, 22947 – 22951. doi.org/10.1002/anie.202010693

[3]Xiaoyan Du, Wenxia Dong, Zhongping Li, * Guangming Wen,* Meng Liu and Xiujun Fan, A novel nanosensor for detecting tetracycline based on fluorescent palladium nanoclusters, New J. Chem., 2020, 44, 9248-9254.

[4]杜丽清，伊雯雯，温广明，李忠平*, 石墨烯量子点／钯纳米复合材料直接电化学法检测葡萄糖, 山西大学学报（自然科学版）2020, 43(1):126-134.

[5]Xiaoyan Du, Zhongping Li⁎, Paper Sensor of Curcumin by Fluorescence Resonance Energy Transfer on Nitrogen-doped Carbon Quantum Dot, Spectrochimica Acta Part A: Molecular and Biomolecular, 2020, 227, 117538 (sci 2区)

[6]Zhongping Li⁎ Wenxia Dong, A novel photoelectrochemical sensor based on g-C3N4@CdS QDs for sensitive detection of Hg2+, Microchemical Journal 152 (2020) 104259 (sci 3区)

[7]Zhongping Li⁎, Chunxiao Han, Palladium nanoflowers supported on amino-fullerene as novel catalyst for reduction of 4-nitrophenol, Chinese Chemical Letters 31(2020)818–820 (IF 4.685, 2区)

[8]伊雯雯，李忠平*，王园琴，李俊芬，董川，基于EDTA功能化石墨烯水质Cu(Ⅱ)电化学传感器，分析科学学报 2019, 35(4):433-437.

[9]Zhongping Li⁎, Yuxin Zhang, Ruiqi Zhu, Guangming Wen, Chuan Dong, Hung-Wing Li⁎, Self-assembled palladium nanoflowers supported on fullerene: Electrochemical catalytic performance for the reduction of 4-nitrophenol, Electrochemistry Communications 104 (2019) 106484. (sci 2区)

[10]Wenwen Yi, Zhongping Li⁎, Chuan Dong, Hung-Wing Li⁎, Junfen Li, Electrochemical detection of chloramphenicol using palladium nanoparticles decorated reduced graphene oxide, Microchemical Journal 148 (2019) 774–783. (sci 3区)

[11]Liqing Du, Zhongping Li⁎, Jiaoli Yao, Guangming Wen, Chuan Dong, Hung-Wing Li，Enzyme free glucose sensing by amino-functionalized silicon quantum dot, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2019, 216, 303–309. (sci 2区)

[12]李忠平, 张凯, 董振宇, 孙美荣, 孙文会, 董川, 可褪色环保划粉的研究, 日用化学工业, 2018 7(48):399-402

[13]Guangming Wen, , Wenxia Dong, Bin Liu, Zhongping Li,⁎, Lifang Fan, A novel nonenzymatic cascade amplification for ultrasensitive photoelectrochemical DNA sensing based on target driven to initiate cyclic assembly of hairpins, Biosensors and Bioelectronics 117 (2018) 91–96

[14]张育宁，李忠平⁎，检测液体食品中维生素C含量方法的研究，农产品加工，2017，12：9-11.

[15]Lei Zhang, Qin Hu, Zhongping Li, Yan Zhang, Dongtao Lu, Shaomin Shuang, Martin M. F. Choi * and Chuan Dong，Chromatographic separation and mass spectrometric analysis of N-acetyl-L-cysteineprotected palladium nanoparticles，Anal. Methods, 2017, 9, 4539.

[16]Zhongping Li, Minna Ruan, Liqing Du, Guangming Wen, Chuan Dong, Hung-Wing Li，Graphene nanomaterials supported palladium nanoparticles as nanocatalysts for electro-oxidation of methanol，Journal of Electroanalytical Chemistry 2017,805,47–52.

[17]Yunfang Guo, Zhongping Li, Liqing Du, Hung-Wing Li, Chuan Dong, 氮掺杂石墨烯量子点/钯纳米复合材料的研究, Journal of Analytical Science, 2017, 33(2),1-4.

[18]Meng Liu, Qiang Zhang, Zhongping Li, Jimmy Gu, John D. Brennan & Yingfu Li，Programming a topologically constrained DNA nanostructure into a sensor，Nature Communications 7（2016）12074.（ DOI: 10.1038/ncomms12074）

[19]Sisi Feng, Fei Jia, Liping Lu, Zhongping Li and Shuo Zhang，An unusual 32-membered copper(II)metallomacrocube based on a Cu4O3X cubic core: photocatalytic, electrocatalytic, and magnetic properties，Chem. Commun., 52（2016）, 4294—4297.

[20]Chung-Yan Poon, Qinghua Li, Jiali Zhang, Zhongping Li, Chuan Dong, Albert Wai-Ming Lee, Wing-Hong Chan, Hung-Wing Li, FRET-based modified graphene quantum dots for direct trypsin quantification in urine, Analytica Chimica Acta 917 (2016) 64-70.

[21]姚娇丽,郭云芳,张佳丽,李忠平,董川, 硅量子点支撑钯纳米粒子的可控制备, 分析科学学报,31(2015),1-5.

[22]Lei Zhang, Zhongping Li, Yan Zhang, Man Chin Paau, Qin Hu, Xiaojuan Gong, Shaomin Shuang, Chuan Dong, Xiaoguang Peng, Martin M.F. Choi，High-performance liquid chromatography coupled with mass spectrometry for analysis of ultrasmall palladium nanoparticles，Talanta, 2015,131: 632-639.

[23]Guangming Wen, Zhongping Li, Martin M.F. Choi, Detection of ethanol in food: A new biosensor based on bacteria, Journal of Food Engineering 118 (2013) 56–61.

[24]Zhongping Li, Jiali Zhang, Yanhong Zhou, Shaomin Shuang, Chuan Dong, Martin M.F. Choi，Electrodeposition of palladium nanoparticles on fullerene modified glassy carbon electrode for methane sensing，Electrochimica Acta 76(2012): 288–291.

[25]Zhongping Li, Xu Wang, Guangming Wen, Shaomin Shuang, Chuan Dong and Martin M. F. Choi, Application of hydrophobic palladium nanoparticles for the development ofelectrochemical glucose biosensor, Biosensors and Bioelectronics, 26 (2011) 4619– 4623.(IF:5.4)

[26]Zhongping Li, Jie Gao, Xuwen Ma, Suozhu Wu, Shaomin Shuang, Chuan Dong, Man Chin Paau, and Martin M. F. Choi, Synthesis and Characterization of n-Alkylamine- Stabilized Palladium Nanoparticles for Electrochemical Oxidation of Methane, J. Phys. Chem. C 114（2010）723–733.

[27]Zhongping Li, Junfen Li, Xu Wu, Shaomin Shuang, Chuan Dong, Martin M. F. Choi. Methane sensor based on nanocomposite of palladium/multi-walled carbon nanotubes grafted with 1,6-hexanediamine，Sensors and Actuators B 139 (2009) 453–459.

[28]ZhongPing Li, Yong Guo, Suo Zhu Wu, Shao Min Shuang, Chuan Dong, Methane sensor based on palladium/MWNT nanocomposites, Chinese Chemical Letters 20 (2009) 608–610.

[29]Li Zhongping, Ma Xuwen; Shuang Shaomin, Dong Chuan, Kinetic spectrophotometric method determination of sulphite based on its additional reaction with pararosaniline, Luminescence, 23(2008) 81-82.

[30]Suozhu Wu, Wenping Cheng, Yan Qiu, Zhongping Li, Shaomin Shuang, Chuan Dong，Fiber optic pH sensor based on mode-filtered light detection，Sensors and Actuators B 144 (2010) 255–259。

[31]SuozhuWu, Yan Zhang, Zhongping Li, Shaomin Shuanga, Chuan Donga, Martin M.F. Choi，Mode-filtered light methane gas sensor based on cryptophane A, Analytica Chimica Acta 633 (2009) 238–243.

[32]Suo Zhu Wu, Shao Min Shuang, Yan Zhang , Zhong Ping Li, Martin M.F. Choi, Cai Hong Zhang, Chuan Dong, Study on mode-filtered light sensor for methane detection, Chinese Chemical Letters 20 (2009) 210–212.

[33]马旭文, 李忠平, 李建晴, 董川, 硫唑嘌呤和巯嘌呤与牛血清白蛋白作用的荧光光谱研究, 分析科学学报, 2008, 24(4),399-403。

[34]上官灵芝, 乔洁, 郭玉晶, 常燕, 李忠平, 董川, 电沉积钯纳米修饰玻碳电极对甲醛的电催化氧化, 武汉大学学报(理学版), 2008,54(6), 661-664。

专利：

[1] 李忠平, 董文娟, 董川, 一种抗氧化食品保鲜, 发明专利号: 431846

[2] 李忠平, 李建晴, 张俊, 双少敏, 董川, 一种亚硫酸钠的稳定剂, 发明专利号: 431846

[3] 李忠平, 张建彪, 高洁, 董川, 双少敏, 可变多色面泥粉及其制备方法, 发明专利号：562583

[4]李忠平, 赵春贵, 张彦, 董川, 双少敏, 一种可变多色面泥粉及其制备方法, 发明专利号：590656

[5] 李忠平，董雪松，张彦，董川，师利民，双少敏，一种钯纳米/多壁碳纳米管复合物及其制备方法和应用，专利公开(公告)号：CN101559937 (公开时间：2009.10.21).

[6] 张利琴, 谭雪荣, 乔洁, 李忠平, 董川, 一种修饰钯电极的制备方法，发明专利号：665132。

[7] 张建彪，闫美芳，李忠平，李振宇，董川，测定果蔬和食用菌蘑菇罐头中二氧化硫含量的试纸，发明专利号：638618

[8] 宋金萍，李忠平，王丽华，鞠东，董川，一种可显色褪色的儿童面泥粉，发明专利号：824913

[9] 李忠平，郭云芳，董川，超分子穴番-A负载钯纳米材料的制备方法及应用，发明专利号ZL201610874404 .2

[10] 李忠平，朱瑞琦，杨振华，张月霞，李红荣，双少敏，董川，一种油溶性石墨烯量子点的制备方法，发明专利号：ZL201710946525.8，

[11] 李忠平，兰月，李红荣，董川，一种彩色可褪色水性喷漆，申请号 201710081496 .3

[12] 李忠平，张凯，张国梅，双少敏，董川，李红荣，一种可褪色黑墨水及其制备方法，申请号 201710400093 .0

[13] 李忠平，刘付永，李红荣，董川，一种裁缝用环保隐迹划粉，申请号 201710080126 .8

[14] 杜丽清，李忠平，张凯，董川，一种纸片型食品保鲜卡，申请号 201710257106 .3

主持和参与项目：

[1]2006年化学修饰光纤瓦斯传感器及化学热力学预警基础研究，国家自然科学基金重点项目（No.50534100 资助金额160万）参与。

[2]2007年大学生创新项目：钯纳米的合成及纳米气体传感器的研制，太原市科技项目（资助3万）。

[3]2011年山西省回国留学人员科研项目：新型纳米甲烷气体传感器的研究（No.2011-014,2013-027资助金额10万）。

[4]2012年山西省社会发展攻关项目：煤矿安全生产-新型电化学瓦斯传感器的研制（No.20120313029-2，资助金额8万）。

[5]2013年基于钯纳米电化学甲烷传感器的研究，国家自然科学青年基金（2013.01-2015.12，No. 21205075，资助金额22.0万）

[6]2017山西省留学回国人员科技活动择优资助项目：SELEX技术在有机相体系中的研究 2016.07-2019.05,(No.2016-8, 5万)。

[7]2018 山西省自然科学基金面上项目：单原子纳米催化剂在甲烷转化中的应用研究, 2019.01-2021.12,NO. 201801D121042（5.0万元）